I wouldn't recommend Shopify or Opencart.
For a scalable adult toy store site like jimmyjane - You need to have a technically strong platform build on a solid tech framework.
You can either go with PHP or Ruby on rails.
We've clients who run marketplace platform with more than 100K products and daily 75 to 150 transactions. ( non-adult )
The same script - we have customized to adult toy store niche with a custom design + drop shipping and adult payment processor.
You can check that out here product detail page - xMarketplace -
adent.io/products/xmarketplace
If you have any questions - let me know.
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